Argentite ore.

No native silver has been found in the district. However, silver occurs as a sulphide - Argentite [AgzS],  particularly along with gold.  It can also be found with minerals such as galena, copper and sphalerite.  When galena was smelted at Wanlockhead and Leadhills, silver was recovered from the smelting process. It was sent to Edinburgh for the minting of coins and jewellery, and exported to Europe.

Silver is a chemical element with the chemical symbol Ag (Latin: argentum, from the Ancient Greek: ἀργήεντος - argēentos, gen. of ἀργήεις - argēeis, "white, shining" ) and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal. The metal occurs naturally in its pure, free form (native silver), as an alloy with gold (electrum) and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a by-product of copper, gold, lead, and zinc refining.

Silver has been known since ancient times and has long been valued as a precious metal, used to make ornaments, jewelry, high-value tableware, utensils (hence the term silverware), and currency coins. Today, silver metal is used in electrical contacts and conductors, in mirrors and in catalysis of chemical reactions. Its compounds are used in photographic film and dilute solutions of silver nitrate and other silver compounds are used as disinfectants. Although the antimicrobial uses of silver have largely been supplanted by the use of antibiotics, further research into its clinical potential is in progress.