GALENA
CHALCOPYRITE
SPHALERITE
GOLD
SILVER
  CHALCOPYRITE  
 

Chalcopyrite is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical composition CuFeS2.It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.On exposure to air, chalcopyrite oxidises to a variety of oxides, hydroxides and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). Chalcopyrite is rarely found in association with native copper.

Identification
Chalcopyrite is often confused with pyrite, although the latter has a cubic and not a tetragonal crystal system. Further, chalcopyrite is often massive, rarely crystalline, and less brittle. Chalcopyrite is also a darker yellow in color, with a greenish tinge and diagnostic greasy luster.Due to its color and high copper content, chalcopyrite has often been referred to as "yellow copper".

Chemistry
Natural chalcopyrite has no solid solution series with any other sulfide minerals. There is limited substitution of Zn with Cu despite chalcopyrite having the same crystal structure as sphalerite.However, it is often contaminated by a variety of other trace elements such as Co, Ni, Mn, Zn and Sn substituting for Cu and Fe. Se, Fe and As substitute for sulfur, and trace amounts of Ag, Au, Pt, Pd, Pb, V, Cr, In, Al and Sb are reported.It is likely many of these elements are present in finely intergrown minerals within the chalcopyrite crystal, for instance lamellae of arsenopyrite representing As, molybdenite representing Mo, etc

       
         
         

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